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Plexcore® OS

Plexcore® OS is a p-type organic semiconductor designed to deliver superior charge transfer control for high-volume production of printed circuitry and power applications. Based on polythiophene chemistry, Plexcore® OS is readily formulated into printable inks with tailored material properties for a wide range of electronic applications.
With electronics-grade purity and high regioregularity, Plexcore® OS delivers commercial-level device performance that is both stable over time and uniform across the device. Produced in Plextronics’ manufacturing facility, Plexcore® OS is available for gram-scale research needs up to multiple-kilogram production quantities.
Plexcore® OS Applications
• Printed Field Effect Transistors
• Plastic Solar Cells
• Printed Memory
• Smart Packaging
• Chemical & Optical Sensors
• Display & Lighting Backplanes
• Smart Textiles |
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Organic Semiconductor Performance Characteristics |
Plexcore® OS
Solution |
Customer
Benefits |
Excellent film formation |
Morphological control by altering molecular weight and application conditions
Forms ordered monolayers on the dielectric surface
Forms crystalline domains
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Uniform device performance
Easy implementation in new production processes
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Easy formulation in various solvent systems |
Soluble in preferred solvents
Polymer chain orientation at interface controllable with solvent system
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Low-temperature solution processable
Print via multiple methods (spin, inkjet, transfer, etc)
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Stable, predictable material properties |
Scaled material production for multi-kilogram supply
Well-established in-device performance
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High-volume production ready
Improved production yield
Lack of defects caused by OS impurities
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Plexcore® OS in Printed Circuitry |
Enables effective current switching |
Electronics-grade purity
High regioregularity
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Low leakage current
High mobility
High on-current
High on/off ratio
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Plexcore® OS in Printed Solar Power |
Efficient light harvesting and hole transport |
Strong light absorber in the visible range
Well matched to fullerene n-types
High hole (positive charge) mobility
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High external quantum efficiency
High fill factor
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Plexcore® OS in Printed Circuitry
The projected $300 billion printed electronics market will only be possible when electronic circuitry can be printed onto flexible surfaces using inexpensive manufacturing processes. Organic field effect transistors (OFETs), the fundamental building block of printed circuitry (see figure 1), drive electronic operation of such printed electronic devices as radio frequency identification (RFID) tags, display backplanes and various types of sensors. The ability to print OFETs onto various substrates at a low-cost creates opportunities to incorporate these devices into a wide variety of applications, including packaging, consumer products and advertising spaces such as electronic billboards. As a result of the cost-driven competition with current applications like bar codes and basic consumer packaging, performance at low-cost and reliability are the market drivers for printed circuitry.
Plexcore® OS is the printed semiconductor in OFETs that controls current flow from the source to the drain electrode when voltage is applied across the gate electrode. The transistor signal is controlled by this gate voltage.

Plexcore® OS in Printed Solar Power
Printed solar power will generate a low-cost source of renewable energy that does not face the economic and raw material challenges of today’s silicon-based solar modules. The world’s appetite for less expensive and cleaner energy has produced a surge of investment in printed solar power, resulting in significant advances in performance and manufacturability. As such, printed solar power is poised to enter the marketplace for applications ranging from solar farms creating megawatts of power to small, portable consumer products.
Plexcore® OS is the p-type semiconductor in the photoactive layer of printed solar cells, which
consists of both a p-type and n-type semiconductor (see figure 2). When sunlight is absorbed by the photoactive layer,
the positive (holes) and negative (electrons) charges separate. Plexcore® OS aids in control of cell voltage and enables easy transport of the positive charges toward the anode, ultimately enabling power generation.

For further information, e-mail ccontie@plextronics.com
Select research-grades of Plexcore OS are available at Sigma Aldrich.
Plexcore OS 1100: High purity P3HT for organic electronics research. Material optimized for use in active layers of OFETs and other devices.
Plexcore OS 1200: High molecular weight; ultra-high purity P3HT optimized for use in organic photovoltaics (OPV) research and devices.
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